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Formation of a dimeric tungsten(i) complex via C–H activation

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Abstract

An aminopyridinato ligand stabilized and coordinatively unsaturated dimeric tungsten(0) complex having an electronic structure with six metal centred HOMOs (σ22222, and δ*2) has been isolated and structurally characterized. Its reaction with a cryptand leads to a C–H bond activation of one of the isopropyl groups of the N-ligand to form a dimeric tungsten(I) complex.

Graphical abstract: Formation of a dimeric tungsten(i) complex via C–H activation

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Article information


Submitted
21 Dec 2019
Accepted
15 Jan 2020
First published
15 Jan 2020

Dalton Trans., 2020, Advance Article
Article type
Paper

Formation of a dimeric tungsten(I) complex via C–H activation

A. Noor, S. Qayyum, S. Schwarz, T. Dietel and R. Kempe, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04847B

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