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A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n-propyl moieties

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Abstract

Crystalline-state photochromism of a rhodium dithionite complex with n-propyl moieties was studied directly by performing single crystal X-ray diffraction experiments; a non-linear relationship between the degree of the conformational change of the n-propyl moiety and the degree of the photochromic reaction of the dithionite group (μ-O2SSO2) was observed at −173 °C.

Graphical abstract: A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n-propyl moieties

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Article information


Submitted
15 Dec 2019
Accepted
02 Jan 2020
First published
03 Jan 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

A non-linear phenomenon observed in the photochromic crystals of a rhodium dithionite complex with n-propyl moieties

H. Nakai, S. Miyata, Y. Kajiwara, Y. Ozawa and M. Abe, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04760C

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