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Issue 7, 2020
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Combining unsaturated metal sites and narrow pores within a Co(ii)-based MOF towards CO2 separation and transformation

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Abstract

A Co(II)-based MOF, {[Co3(L)2(bpb)(DMA)(H2O)]·Solvents}n (RH-1), with a unique interpenetrated framework has been solvothermally prepared. Because of its unsaturated metal sites and narrow pores inside the framework, RH-1 demonstrated excellent selective CO2 adsorption over N2 and CH4 and good performance in catalytic CO2 conversion to cyclic carbonates under mild conditions.

Graphical abstract: Combining unsaturated metal sites and narrow pores within a Co(ii)-based MOF towards CO2 separation and transformation

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Article information


Submitted
13 Dec 2019
Accepted
20 Jan 2020
First published
20 Jan 2020

Dalton Trans., 2020,49, 2058-2062
Article type
Communication

Combining unsaturated metal sites and narrow pores within a Co(II)-based MOF towards CO2 separation and transformation

X. Zhang, R. Zhang, H. Hu, L. Geng, Y. Zhang, J. Gao, D. Zhang, Y. Jin and J. Sheng, Dalton Trans., 2020, 49, 2058
DOI: 10.1039/C9DT04736K

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