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A fast and simple B-C bond-forming in metallacarboranes avoiding halometallacarboranes and transition metal catalysts

Abstract

It is reported for the first time an electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ. This new synthetic methodology opens a new perspective on easy metallacarborane derivatization with organic fragments that widens the properties of both fragments enhancing their possible applications.

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Article information


Submitted
10 Dec 2019
Accepted
11 Feb 2020
First published
11 Feb 2020

This article is Open Access

Dalton Trans., 2020, Accepted Manuscript
Article type
Paper

A fast and simple B-C bond-forming in metallacarboranes avoiding halometallacarboranes and transition metal catalysts

A. B. Buades, Z. Kelemen, V. S. Arderiu, A. Zaulet, C. Vinas and F. Teixidor, Dalton Trans., 2020, Accepted Manuscript , DOI: 10.1039/C9DT04695J

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