Jump to main content
Jump to site search


Effect of metal ion substitution on the catalytic activity of a pentanuclear metal complex

Author affiliations

Abstract

A pentanuclear cobalt complex that consists of five cobalt ions and six bpp ligands (Co5, Hbpp = 3,5-bis(2-pyridyl)pyrazole) was synthesized and crystallographically characterized. Electrochemical measurements indicate that Co5 has multielectron transfer ability. We also found that Co5 reduces CO2 to CO under photoirradiation in the presence of a photosensitizer.

Graphical abstract: Effect of metal ion substitution on the catalytic activity of a pentanuclear metal complex

Back to tab navigation

Supplementary files

Article information


Submitted
09 Dec 2019
Accepted
06 Jan 2020
First published
07 Jan 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Effect of metal ion substitution on the catalytic activity of a pentanuclear metal complex

T. Akai, M. Kondo, S. K. Lee, H. Izu, T. Enomoto, M. Okamura, Y. Saga and S. Masaoka, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04684D

Social activity

Search articles by author

Spotlight

Advertisements