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Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate

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Abstract

A novel decahydrodecaborate-functionalized Anderson type polyoxometalate has been synthesized and characterized in solution by ESI-MS, various NMR techniques and electrochemical methods. DFT studies provide strong support to understand the properties of this hybrid system.

Graphical abstract: Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate

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Article information


Submitted
09 Dec 2019
Accepted
12 Mar 2020
First published
13 Mar 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate

M. Diab, A. Mateo, J. Al Cheikh, M. Haouas, A. Ranjbari, F. Bourdreux, D. Naoufal, E. Cadot, C. Bo and S. Floquet, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04676C

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