Issue 15, 2020
From the journal:

Dalton Transactions

Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate†

Manal Diab,ab   Ana Mateo, ORCID logo c   Joumada Al Cheikh,d   Mohamed Haouas, ORCID logo a   Alireza Ranjbari,de   Flavien Bourdreux,a   Daoud Naoufal,*b   Emmanuel Cadot,a   Carles Bo*cf  and  Sébastien Floquet ORCID logo *a  

* Corresponding authors

a Institut Lavoisier de Versailles, CNRS, UVSQ, Université Paris-Saclay, 45 av. des Etats-Unis, Versailles, France
E-mail: sebastien.floquet@uvsq.fr

b Laboratory of Inorganic and Organometallic Coordination Chemistry, LCIO, Lebanese University, Faculty of Sciences I, Hadath, Lebanon

c Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology, Av. Països Catalans 16, Tarragona, Spain

d Equipe de Recherche et Innovation en Electrochimie pour l’énergie (ERIEE), Institut de Chimie Moléculaire et des matériaux d’Orsay (ICMMO), UMR CNRS 8182, Université Paris-Sud, Université Paris-Saclay, 91405 Orsay, France

e Université Paris-Saclay, Institut de Chimie Physique, ((ICP) UMR8000 CNRS), 91405, Orsay, France

f Departament de Química Física i Inorgànica, Universitat Rovirai Virgili, Marcelí Domingo s/n, Tarragona, Spain

Abstract

A novel decahydrodecaborate-functionalized Anderson type polyoxometalate has been synthesized and characterized in solution by ESI-MS, various NMR techniques and electrochemical methods. DFT studies provide strong support to understand the properties of this hybrid system.

Graphical abstract: Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate

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Article information

DOI
https://doi.org/10.1039/C9DT04676C
Article type
Communication
Submitted
09 Dec 2019
Accepted
12 Mar 2020
First published
13 Mar 2020

Dalton Trans., 2020,49, 4685-4689

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Unprecedented coupling reaction between two anionic species of a closo-decahydrodecaborate cluster and an Anderson-type polyoxometalate

M. Diab, A. Mateo, J. Al Cheikh, M. Haouas, A. Ranjbari, F. Bourdreux, D. Naoufal, E. Cadot, C. Bo and S. Floquet, Dalton Trans., 2020, 49, 4685 DOI: 10.1039/C9DT04676C

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