Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination

Junhui Bao; Shanshan Wu; Xin Xu; Liping Huang; Liwei Zhang; Jehan Kim; Xiantai Zhou; Yaju Chen; Hongbing Ji; Zhegang Huang

doi:10.1039/C9DT04668B

Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination†

Junhui Bao,

‡^a Shanshan Wu,‡^a Xin Xu,^a Liping Huang,

^a Liwei Zhang,^a Jehan Kim,^b Xiantai Zhou,^c Yaju Chen,

^d Hongbing Ji

*^a and Zhegang Huang

*^a

Author affiliations

* Corresponding authors

^a Fine Chemical Industry Research Institute and PCFM Lab, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, PR China
E-mail: huangzhg3@mail.sysu.edu.cn, jihb@mail.sysu.edu.cn

^b Pohang Accelerator Laboratory, Posttech, Pohang, Gyeongbuk, Korea

^c School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, PR China

^d School of Chemistry, Guangdong University of Petrochemical Technology, Maoming 525000, PR China

Abstract

A tubular MOF with adequate active sites is prepared by the bending of metal-coordinated honeycombed frameworks via titration and shows fast catalytic kinetics with lower catalytic loading for CO₂ conversion. The TON is observed to be 2300 and the corresponding TOF of up to 173 h⁻¹ is achieved for the first time.

Dalton Transactions

Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination†

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Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination

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