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Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination

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Abstract

A tubular MOF with adequate active sites is prepared by the bending of metal-coordinated honeycombed frameworks via titration and shows fast catalytic kinetics with lower catalytic loading for CO2 conversion. The TON is observed to be 2300 and the corresponding TOF of up to 173 h−1 is achieved for the first time.

Graphical abstract: Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination

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Article information


Submitted
07 Dec 2019
Accepted
06 Jan 2020
First published
06 Jan 2020

Dalton Trans., 2020, Advance Article
Article type
Communication

Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination

J. Bao, S. Wu, X. Xu, L. Huang, L. Zhang, J. Kim, X. Zhou, Y. Chen, H. Ji and Z. Huang, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04668B

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