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1-D manganese(ii)-terpyridine coordination polymers as precatalysts for hydrofunctionalisation of carbonyl compounds

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Abstract

Reductive catalysis with earth-abundant metals is currently of increasing importance and shows potential in replacing precious metal catalysis. In this work, we revealed catalytic hydroboration and hydrosilylation of ketones and aldehydes achieved by a structurally defined manganese(II) coordination polymer (CP) as a precatalyst under mild conditions. The manganese-catalysed methodology can be applied to a range of functionalized aldehydes and ketones with turnover numbers (TON) of up to 990. Preliminary results on the regioselective catalytic hydrofunctionalization of styrenes by the Mn-CP catalyst are also presented.

Graphical abstract: 1-D manganese(ii)-terpyridine coordination polymers as precatalysts for hydrofunctionalisation of carbonyl compounds

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Article information


Submitted
04 Dec 2019
Accepted
28 Jan 2020
First published
29 Jan 2020

Dalton Trans., 2020, Advance Article
Article type
Paper

1-D manganese(II)-terpyridine coordination polymers as precatalysts for hydrofunctionalisation of carbonyl compounds

G. Zhang, H. Zeng, S. Li, J. Johnson, Z. Mo, M. C. Neary and S. Zheng, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04637B

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