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Issue 8, 2020
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Trigonal bipyramidal Co III2Dy3 cluster exhibiting single-molecule magnet behavior

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Abstract

A heterometallic 3d–4f compound formulated as {[CoIII2Dy3Na(CH3CH2COO)6(OH)6(NO3)4(H2O)2]·H2O}n (1) has been synthesized and structurally characterized. The Co2Dy3 metal core adopts trigonal bipyramidal (TBP) geometry. Compound 1 displays single-molecule magnet behavior with an energy barrier of 60.3 K under a zero dc field.

Graphical abstract: Trigonal bipyramidal CoIII2Dy3 cluster exhibiting single-molecule magnet behavior

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Article information


Submitted
02 Dec 2019
Accepted
06 Feb 2020
First published
07 Feb 2020

Dalton Trans., 2020,49, 2421-2425
Article type
Communication

Trigonal bipyramidal CoIII2Dy3 cluster exhibiting single-molecule magnet behavior

H. Lun, X. Kong, L. Long and L. Zheng, Dalton Trans., 2020, 49, 2421
DOI: 10.1039/C9DT04600C

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