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Reductive halocyclosilazane polymerization

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Abstract

The synthesis of a chloro-functionalized six-membered cyclosilazane (Si5N) is reported. Subsequent reductive polymerizations yielded low molecular weight polysilazanes. 1H and 29Si NMR characterization suggest the identity of the reducing metal influences the polysilazane structure. Optical characterization is consistent with extended σ-conjugation upon polymerization.

Graphical abstract: Reductive halocyclosilazane polymerization

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Article information


Submitted
19 Nov 2019
Accepted
23 Jan 2020
First published
24 Jan 2020

Dalton Trans., 2020, Advance Article
Article type
Paper

Reductive halocyclosilazane polymerization

C. P. Folster, P. N. Nguyen and R. S. Klausen, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04468J

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