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Heterobimetallic scandium–group 10 metal complexes with LM → Sc (LM = Ni, Pd, Pt) dative bonds

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Abstract

Heterobimetallic scandium complexes with whole group 10 metals were synthesized. All Sc–LM complexes were characterized by NMR spectroscopy, X-ray diffraction analysis and computational studies, which revealed notable LM → Sc (LM = Ni, Pd, Pt) dative bonding interactions in these heterobimetallic systems. Versatile coordination modes toward apical donors were observed in these heterobimetallic Sc–LM complexes, among which the Sc–Ni complexes 2 and 3 were reversibly bound to N2 and the Sc–Pt complex 5 was coordinated to an additional PPh3 ligand, while in the Sc–Pd complex 4 no apical donor was ligated.

Graphical abstract: Heterobimetallic scandium–group 10 metal complexes with LM → Sc (LM = Ni, Pd, Pt) dative bonds

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Publication details

The article was received on 30 Sep 2019, accepted on 20 Nov 2019 and first published on 21 Nov 2019


Article type: Paper
DOI: 10.1039/C9DT04369A
Dalton Trans., 2020, Advance Article

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    Heterobimetallic scandium–group 10 metal complexes with LM → Sc (LM = Ni, Pd, Pt) dative bonds

    P. Cui, C. Xiong, J. Du, Z. Huang, S. Xie, H. Wang, S. Zhou, H. Fang and S. Wang, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04369A

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