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A mixed-ligand strategy regulates thorium-based MOFs

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Abstract

Two novel thorium-based organic frameworks (Th-IHEP-5 and Th-IHEP-6) were assembled from a hexanuclear thorium cluster, porphyrin derivative ligand and linear carboxylic acid ligands via a mixed-ligand strategy. As a stable heterogeneous catalyst, Th-IHEP-5 exhibited high photocatalytic activity for the oxidation of 2-chloroethyl ethyl sulfide (CEES) and the fixation of CO2. The good catalytic effect is attributed to the large conjugated system of porphyrin and the photosensitizer enhancing effects of bipyridine.

Graphical abstract: A mixed-ligand strategy regulates thorium-based MOFs

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Supplementary files

Article information


Submitted
25 Oct 2019
Accepted
19 Dec 2019
First published
20 Dec 2019

Dalton Trans., 2020, Advance Article
Article type
Communication

A mixed-ligand strategy regulates thorium-based MOFs

Z. Huang, K. Hu, L. Mei, X. Kong, J. Yu, K. Liu, L. Zeng, Z. Chai and W. Shi, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT04158C

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