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Ba8SrPb24O24Cl18: the first alkali-earth metal lead(ii) oxyhalide with an intriguing multimember-ring layer

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Abstract

The first alkali-earth metal lead(II) oxyhalide Ba8SrPb24O24Cl18 characterized by fascinating multimember-ring layers has been discovered. Theoretical and experimental investigations illustrate that Ba8SrPb24O24Cl18 exhibits a moderate band gap of 3.09 eV, incongruent melting behavior and birefringence of 0.014@1064 nm. This discovery may offer new ideas for regulating the optical properties of oxyhalides and broadening their structural diversity.

Graphical abstract: Ba8SrPb24O24Cl18: the first alkali-earth metal lead(ii) oxyhalide with an intriguing multimember-ring layer

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Publication details

The article was received on 09 Jul 2019, accepted on 17 Aug 2019 and first published on 19 Aug 2019


Article type: Communication
DOI: 10.1039/C9DT02839K
Dalton Trans., 2020, Advance Article

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    Ba8SrPb24O24Cl18: the first alkali-earth metal lead(II) oxyhalide with an intriguing multimember-ring layer

    Z. Li, S. Zhang, W. Xing, Z. Lin, J. Yao and Y. Wu, Dalton Trans., 2020, Advance Article , DOI: 10.1039/C9DT02839K

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