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Issue 12, 2020
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Ba8SrPb24O24Cl18: the first alkali-earth metal lead(ii) oxyhalide with an intriguing multimember-ring layer

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Abstract

The first alkali-earth metal lead(II) oxyhalide Ba8SrPb24O24Cl18 characterized by fascinating multimember-ring layers has been discovered. Theoretical and experimental investigations illustrate that Ba8SrPb24O24Cl18 exhibits a moderate band gap of 3.09 eV, incongruent melting behavior and birefringence of 0.014@1064 nm. This discovery may offer new ideas for regulating the optical properties of oxyhalides and broadening their structural diversity.

Graphical abstract: Ba8SrPb24O24Cl18: the first alkali-earth metal lead(ii) oxyhalide with an intriguing multimember-ring layer

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Article information


Submitted
09 Jul 2019
Accepted
17 Aug 2019
First published
19 Aug 2019

Dalton Trans., 2020,49, 3667-3671
Article type
Communication

Ba8SrPb24O24Cl18: the first alkali-earth metal lead(II) oxyhalide with an intriguing multimember-ring layer

Z. Li, S. Zhang, W. Xing, Z. Lin, J. Yao and Y. Wu, Dalton Trans., 2020, 49, 3667
DOI: 10.1039/C9DT02839K

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