Preparation and luminescence properties of a M16 heterometallic coinage metal chalcogenide cluster

Alexander M. Polgar; Yannick J. Franzke; Sergei Lebedkin; Florian Weigend; John F. Corrigan

doi:10.1039/C9DT02669J

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Preparation and luminescence properties of a M₁₆ heterometallic coinage metal chalcogenide cluster†

Alexander M. Polgar,^a Yannick J. Franzke,

^b Sergei Lebedkin,^c Florian Weigend

*^c and John F. Corrigan

*^ad

Author affiliations

* Corresponding authors

^a Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7, Canada
E-mail: corrigan@uwo.ca

^b Institut für Physikalische Chemie, Karlsruher Institut für Technologie (KIT), Kaiserstr. 12, 76131 Karlsruhe, Germany

^c Institut für Nanotechnologie, Karlsruher Institut für Technologie (KIT), Campus Nord, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
E-mail: florian.weigend@kit.edu

^d Centre for Advanced Materials and Biomaterials Research, The University of Western Ontario, London, Ontario N6A 3 K7, Canada

Abstract

A hexadeca-nuclear, N-heterocyclic carbene stabilized gold(I)–copper(I)-sulfido cluster is reported, which emits yellow-orange in the solid state. The nature of this emission is examined, supported by combined theoretical and spectroscopic studies.

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Article information

DOI: https://doi.org/10.1039/C9DT02669J
Article type: Communication
Submitted: 25 Jun 2019
Accepted: 10 Dec 2019
First published: 17 Dec 2019

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Dalton Trans., 2020,49, 593-597

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Preparation and luminescence properties of a M₁₆ heterometallic coinage metal chalcogenide cluster

A. M. Polgar, Y. J. Franzke, S. Lebedkin, F. Weigend and J. F. Corrigan, Dalton Trans., 2020, 49, 593 DOI: 10.1039/C9DT02669J

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