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Issue 20, 2020
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Photocatalyzed allylic derivatization reactions

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Abstract

Catalytic allylation reactions are important methodologies to introduce the versatile allyl functionality into molecules to produce fine chemicals and synthetic building blocks. Since the first reports by Tsuji and Trost, many improvements on allylation technologies have been reported. The introduction of photocatalytic techniques marked one of the major breakthroughs in this field, complementing the existing thermal chemo-catalyzed protocols, providing high selectivity under milder conditions. This review discloses state-of-the-art photocatalyzed allylation methodologies, their reaction mechanisms, and synthetic applications. The reactions are classified according to the employed catalysts, namely single photocatalyst and dual-catalytic approaches. Finally, each methodology is individually presented and evaluated based on the performance of the reaction.

Graphical abstract: Photocatalyzed allylic derivatization reactions

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Article information


Submitted
08 Jul 2020
Accepted
28 Aug 2020
First published
28 Aug 2020

Catal. Sci. Technol., 2020,10, 6754-6768
Article type
Minireview

Photocatalyzed allylic derivatization reactions

P. Hünemörder and E. Mejía, Catal. Sci. Technol., 2020, 10, 6754
DOI: 10.1039/D0CY01377C

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