The potential of d6 non-noble metal NHC catalysts for carbon dioxide hydrogenation: group and row effects

Yaru Jing; Zongren Ye; Jiaqi Su; Yishun Feng; Ling-Bo Qu; Yan Liu; Zhuofeng Ke

doi:10.1039/D0CY01125H

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The potential of d⁶ non-noble metal NHC catalysts for carbon dioxide hydrogenation: group and row effects†

Yaru Jing,

^a Zongren Ye,

^b Jiaqi Su,^a Yishun Feng,^b Ling-Bo Qu,^c Yan Liu

*^a and Zhuofeng Ke

*^b

Author affiliations

* Corresponding authors

^a School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, P. R. China
E-mail: yanliu@gdut.edu.cn

^b School of Materials Science and Engineering, PCFM Lab, Sun Yat-sen University, Guangzhou 510275, P. R. China
E-mail: kezhf3@mail.sysu.edu.cn

^c College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China

Abstract

A series of d⁶ non-noble transition metal complexes were designed and studied computationally for the hydrogenation of CO₂ to formic acid. Catalysts with a metal of weak electronegativity and low oxidation state show improved potentials. Group VIB catalysts are predicted to be promising candidates, although less attention has been paid so far.

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Article information

DOI: https://doi.org/10.1039/D0CY01125H
Article type: Communication
Submitted: 04 Jun 2020
Accepted: 16 Jul 2020
First published: 21 Jul 2020

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Catal. Sci. Technol., 2020,10, 5443-5447

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The potential of d⁶ non-noble metal NHC catalysts for carbon dioxide hydrogenation: group and row effects

Y. Jing, Z. Ye, J. Su, Y. Feng, L. Qu, Y. Liu and Z. Ke, Catal. Sci. Technol., 2020, 10, 5443 DOI: 10.1039/D0CY01125H

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