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Fabrication of CuZn-Based Catalyst via Polyethylene Glycol Surfactant and Supercritical Drying

Abstract

CuZn-based catalysts have been applied in industrial methanol synthesis. However, in alcohol-assisted low-temperature methanol synthesis (LT-MS), preparation of highly efficient CuZn-based catalysts is still a considerable challenge. Here, we report two optimized strategies that use polyethylene glycol (PEG) surfactant and supercritical CO2 drying in urea co-precipitation method, to synthesize the highly efficient CuZn-based catalysts. The PEG treatment is utilized to enhance porosity and improve surface functional groups of the CuZn-based catalysts, and the supercritical CO2 drying is employed to increase reduction degree for them. The catalytic results of alcohol-assisted LT-MS reveal that via the two optimized strategies, a CuZn-SC-P5 catalyst exhibits superior catalytic performance. It is significantly different from the CuZn-based catalysts prepared by traditional impregnation method, and also better than the catalysts treated by sole PEG treatment or supercritical CO2 drying. The present work provides multiple strategies to improve catalytic efficiency, and will be beneficial to explore new approaches in catalyst synthesis.

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Article information


Submitted
10 May 2020
Accepted
11 Oct 2020
First published
12 Oct 2020

Catal. Sci. Technol., 2020, Accepted Manuscript
Article type
Paper

Fabrication of CuZn-Based Catalyst via Polyethylene Glycol Surfactant and Supercritical Drying

P. Zhang, X. Peng, Y. Araki, Y. Fang, Y. Zeng, R. Kosol, G. Yang and N. Tsubaki, Catal. Sci. Technol., 2020, Accepted Manuscript , DOI: 10.1039/D0CY00961J

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