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cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(v)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2

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Abstract

Highly cis-specific (Z selective) ring opening metathesis polymerisation of cycloheptene (CHPE) as well as norbornene has been demonstrated using (pentafluorophenylimido)vanadium(V)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2; the molecular weight of poly(CHPE) increased with increasing polymer yield.

Graphical abstract: cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(v)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2

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Article information


Submitted
14 Apr 2020
Accepted
22 Jun 2020
First published
23 Jun 2020

Catal. Sci. Technol., 2020, Advance Article
Article type
Paper

cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(V)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2

K. Nomura and S. Chaimongkolkunasin, Catal. Sci. Technol., 2020, Advance Article , DOI: 10.1039/D0CY00938E

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