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Issue 14, 2020
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Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt

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Abstract

We report the catalytic and transition metal-free reductive deoxygenation of esters to ethers through the use of a hydrosilane and a fluorinated borate BArF salt as a catalyst. Experimental and theoretical studies support the role of noncovalent interactions between the fluorinated catalyst, the hydrosilane and the ester substrate in the reaction mechanism.

Graphical abstract: Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt

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Article information


Submitted
16 Apr 2020
Accepted
14 Jun 2020
First published
15 Jun 2020

Catal. Sci. Technol., 2020,10, 4586-4592
Article type
Paper

Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt

V. Rysak, R. Dixit, X. Trivelli, N. Merle, F. Agbossou-Niedercorn, K. Vanka and C. Michon, Catal. Sci. Technol., 2020, 10, 4586
DOI: 10.1039/D0CY00775G

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