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Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

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Abstract

The selective and high-yield production of α-olefins by alcohol dehydration is challenging because the isomerization and polymerization olefin products are more thermodynamically stable. In this study, we prepared a physical mixture of nano-sized alumina (Al2O3n) and thoria (ThO2) with high efficiency and selectivity towards the production of α-olefins from stearic alcohol (100% conversion, 92% yield of α-olefin, rate: 2.925 mmol g−1 h−1, solvent: dodecane, 300 °C). To the best of our knowledge, this is the most efficient system developed for fatty α-olefin production from fatty alcohols, as compared to literature. Dehydration experiments of cis- and trans-2-methyl cyclohexanol over Al2O3n revealed the reaction to proceed by anti-elimination, which was favored by the abundance of Lewis acidic sites (LAS, 0.457 mmol g−1) and Lewis basic sites (LBS, 0.567 mmol g−1) on the porous surface of Al2O3n. LAS adsorbed and eliminated the hydroxyl groups (–OH) of stearic alcohol, generating a carbonium ion (carbocation) intermediate, which was subsequently, converted to the alkene as final products over the LBS. However, the selectivity and yield of α-olefin were comparatively low over pure Al2O3n due to the formation of isomeric olefin products. Interestingly, the addition of ThO2 increased yield of α-olefin up to 92% owing to the strong adsorption of this compound on the catalytic surface at high temperatures (300 °C), as evidenced by in situ Fourier transform infrared spectroscopy (FTIR)-ethylene adsorption analyses. Consequently, ThO2 hindered the undesired isomerization and oligomerization of α-olefin taking place over LAS, thereby enhancing the yield of α-olefin products.

Graphical abstract: Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

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Supplementary files

Article information


Submitted
19 Mar 2020
Accepted
06 May 2020
First published
07 May 2020

Catal. Sci. Technol., 2020, Advance Article
Article type
Paper

Selective synthesis of α-olefins by dehydration of fatty alcohols over alumina–thoria mixed catalysts

A. Ali and C. Zhao, Catal. Sci. Technol., 2020, Advance Article , DOI: 10.1039/D0CY00551G

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