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Issue 6, 2020
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Reductant composition influences the coordination of atomically dispersed Rh on anatase TiO2

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Abstract

Atomically dispersed noble metal catalysts have received recent interest, although the coordination of the metal to the support and how this is influenced by pre-treatment have not often been elucidated. We combine CO FTIR-TPD and DFT to distinguish how catalyst reduction via CO or H2 influence the local metal coordination and molecular desorption processes.

Graphical abstract: Reductant composition influences the coordination of atomically dispersed Rh on anatase TiO2

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Article information


Submitted
23 Jan 2020
Accepted
14 Feb 2020
First published
17 Feb 2020

Catal. Sci. Technol., 2020,10, 1597-1601
Article type
Communication
Author version available

Reductant composition influences the coordination of atomically dispersed Rh on anatase TiO2

C. Asokan, H. V. Thang, G. Pacchioni and P. Christopher, Catal. Sci. Technol., 2020, 10, 1597
DOI: 10.1039/D0CY00146E

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