Jump to main content
Jump to site search

Issue 6, 2020
Previous Article Next Article

Effects of alkali metal promoters on the structure–performance relationship of CoMn catalysts for Fischer–Tropsch synthesis

Author affiliations

Abstract

The effects of various alkali metal promoters on the structure–performance relationship of cobalt–manganese (CoMn) catalysts for the Fischer–Tropsch synthesis (FTS) reaction have been investigated. The electronic promotion effects are correlated with the ionic potential (IP) of the alkali metals, which represents their electronic polarizability. The presence of alkali metal promoters in the CoMn catalysts is beneficial for the formation and stabilization of the Co2C phase. With an increase in the IP of the alkali metal promoters, the active phase was found to transition from Co2C nanospheres to Co2C nanoprisms and then to a mixture of fcc Co0 and Co2C nanospheres. In addition, the catalytic performance also changed with the transition in the active phase. For the Co2C nanospheres, high CH4 selectivity and low activity were observed. A promising catalytic performance for Fischer–Tropsch to olefins (FTO) with low CH4 selectivity and high C2–4= selectivity was achieved for the Co2C nanoprisms. However, low C2–4= selectivity with high activity was found for a mixture of fcc Co0 and Co2C nanospheres. It is suggested that the alkali metal promoters in the CoMn catalysts have two different promotion effects that are enhanced with IP: (1) the electronic effect to enhance the CO dissociation probability and benefit the formation of Co2C and (2) the facet stabilization effect to stabilize the Co2C nanoprisms with specific exposed (101) and (020) facets under the FTO reaction conditions.

Graphical abstract: Effects of alkali metal promoters on the structure–performance relationship of CoMn catalysts for Fischer–Tropsch synthesis

Back to tab navigation

Supplementary files

Article information


Submitted
03 Dec 2019
Accepted
02 Feb 2020
First published
03 Feb 2020

Catal. Sci. Technol., 2020,10, 1816-1826
Article type
Paper

Effects of alkali metal promoters on the structure–performance relationship of CoMn catalysts for Fischer–Tropsch synthesis

Z. Li, N. Yao, J. Cen, X. Li, L. Zhong, Y. Sun and M. He, Catal. Sci. Technol., 2020, 10, 1816
DOI: 10.1039/C9CY02441G

Social activity

Search articles by author

Spotlight

Advertisements