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Issue 22, 2020
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Applications of diazaphospholene hydrides in chemical catalysis

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Abstract

Diazaphospholenes have recently emerged as main-group hydride transfer catalysts. This review will briefly summarize the common structural variants of diazaphospholenes, and the properties that make them superb hydride transfer catalysts, followed by a critical examination of the various preparative routes toward diazaphospholenes. Finally, an in-depth examination of the reactivity of diazaphospholenes in contemporary catalysis, including asymmetric catalysis will be undertaken.

Graphical abstract: Applications of diazaphospholene hydrides in chemical catalysis

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Article information


Submitted
01 May 2020
First published
20 Oct 2020

Chem. Soc. Rev., 2020,49, 8335-8353
Article type
Review Article

Applications of diazaphospholene hydrides in chemical catalysis

A. W. H. Speed, Chem. Soc. Rev., 2020, 49, 8335 DOI: 10.1039/D0CS00476F

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