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Iron- and cobalt-catalyzed C(sp3)–H bond functionalization reactions and their application in organic synthesis

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Abstract

Direct C–H bond functionalization catalyzed by non-precious transition metals is an attractive strategy in synthetic chemistry. Compared with the precious metals rhodium, palladium, ruthenium, and iridium commonly used in this field, catalysis based on non-precious metals, especially the earth-abundant ones, is appealing due to the increasing demand for environmentally benign and sustainable chemical processes. Herein, developments in iron- and cobalt-catalyzed C(sp3)–H bond functionalization reactions are described, with an emphasis on their applications in organic synthesis, i.e., the synthesis of natural products and pharmaceuticals and/or their modification.

Graphical abstract: Iron- and cobalt-catalyzed C(sp3)–H bond functionalization reactions and their application in organic synthesis

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Article information


Submitted
08 Apr 2020
First published
22 Jun 2020

Chem. Soc. Rev., 2020, Advance Article
Article type
Review Article

Iron- and cobalt-catalyzed C(sp3)–H bond functionalization reactions and their application in organic synthesis

Y. Liu, T. You, H. Wang, Z. Tang, C. Zhou and C. Che, Chem. Soc. Rev., 2020, Advance Article , DOI: 10.1039/D0CS00340A

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