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Surface-confined single-layer covalent organic frameworks: design, synthesis and application

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Abstract

Two-dimensional (2D) nanomaterials, such as graphene and single layer covalent organic frameworks (sCOFs) are being widely studied due to their unusual structure/property relationships. sCOFs typically feature atomic thickness, intrinsic nanoscale porosity and a crystalline lattice. Compared to other organic 2D materials, sCOFs exhibit major advantages including topological designation and constitutional tunability. This review describes the state of the art of surface-confined sCOFs, emphasizing reticular design, synthesis approaches, and key challenges related to improving quality and exploring applications.

Graphical abstract: Surface-confined single-layer covalent organic frameworks: design, synthesis and application

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Article information


Submitted
10 Dec 2019
First published
06 Mar 2020

Chem. Soc. Rev., 2020, Advance Article
Article type
Tutorial Review

Surface-confined single-layer covalent organic frameworks: design, synthesis and application

D. Cui, D. F. Perepichka, J. M. MacLeod and F. Rosei, Chem. Soc. Rev., 2020, Advance Article , DOI: 10.1039/C9CS00456D

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