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Impact of the olefin structure on the catalytic cycle and decomposition rates of Hoveyda-Grubbs metathesis catalyst

Abstract

A relatively fast degradation of ruthenium catalysts in the presence of selected olefins, and ethylene in particular, is one of the bottlenecks in their use in metathesis reaction. Here we explore the structure-activity relationships between the rate of degradation of Hoveyda-Grubbs catalyst and the structure of olefins by means of DFT calculations. We show that the (Z)-1,2-dichloroethene can't form stable complexes with 14-electron active complex due to strong inductive electron withdrawal effect. Hoveyda-Grubbs catalyst can be, however, used to convert (Z)-1,2-dichloroethene to (E)-1,2-dichloroethene due to differences in crucial barriers in the catalytic cycle for E/Z isomers. Hoveyda-Grubbs catalyst in the presence of both isomers of 1,2-dimethoxyethene and 1,2-dichloroethene are predicted to be very stable in the unproductive metathesis, while for monosubstituted olefins the methoxyethene presence gives relatively low barriers for crucial degradation transition states and can readily undergo decomposition.

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Article information


Submitted
02 Apr 2020
Accepted
21 May 2020
First published
21 May 2020

Phys. Chem. Chem. Phys., 2020, Accepted Manuscript
Article type
Paper

Impact of the olefin structure on the catalytic cycle and decomposition rates of Hoveyda-Grubbs metathesis catalyst

M. Jawiczuk, K. Młodzikowska and B. Trzaskowski, Phys. Chem. Chem. Phys., 2020, Accepted Manuscript , DOI: 10.1039/D0CP01798A

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