A surface modifier enhances the performance of the all-inorganic CsPbI2Br perovskite solar cells with efficiencies approaching 15%

Abstract

All-inorganic perovskite solar cells (PSCs) are attracting considerable attention due to their promising thermal stability, but their inferior power-conversion efficiencies (PCE) hinder their realistic application. Here, we propose an approach through surface modification based on methyl ammonium halide (MAX) for inorganic CsPbI₂Br solar cells processed at a low temperature. The combined benefits of the introduced MAX modifier enable the boosting of the power conversion efficiency to 14.8% with an impressive FF of 82.2% in CsPbI₂Br PSCs. Our experimental analyses coupled with optical modeling indicate that the incorporated MAX leads to an effective passivation of the surface traps originating from Pb²⁺ and I⁻ ions in CsPbI₂Br and simultaneously mediates the crystallization of CsPbI₂Br with slightly enlarged grains and reduced numbers of structural defects and pinhole. As a result, the interfacial trap-assisted recombination is suppressed and the charge extraction is promoted. Mechanistically, we show that in the presence of MAX, the deep-level traps in the perovskites are passivated, leaving the energy of the trapping centers to become shallower. In this situation, the negative impacts of the traps on carrier transport and recombination are mitigated.