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Direct EPR detection of atomic nitrogen in an atmospheric nitrogen plasma jet

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Abstract

In this study, an atmospheric nitrogen plasma jet generated by a custom-built micro-plasma device was analyzed at room temperature by continuous wave and pulse EPR spectroscopy in real time. Transiently formed nitrogen atoms were detected without the necessity to use spin-traps or other reagents for their stabilization. In contrast to results from optical emission spectroscopy, only signals from the 4S ground state of 14N and 15N could be detected. EPR data analysis revealed an isotropic g value of 1.9971 and isotropic hyperfine coupling constants of a(14N) = (10.47 ± 0.02) MHz and a(15N) = (14.69 ± 0.02) MHz. Moreover, lifetime and relaxation data could be determined; both are discussed in terms of spectral widths and actual concentrations of the transiently formed nitrogen species within the plasma jet. The data show that the lifetimes of atomic nitrogen and charged particles such as N+ must be different, and for the latter below the observation time window of EPR spectroscopy. We demonstrate that the real-time (pulsed) EPR technique is a fast and reliable alternative to detect atomic nitrogen in atmospheric pressure plasma jets. The method may be used for a continuous monitoring of the quality of plasma jets.

Graphical abstract: Direct EPR detection of atomic nitrogen in an atmospheric nitrogen plasma jet

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Article information


Submitted
24 Oct 2019
Accepted
03 Feb 2020
First published
03 Feb 2020

Phys. Chem. Chem. Phys., 2020, Advance Article
Article type
Paper

Direct EPR detection of atomic nitrogen in an atmospheric nitrogen plasma jet

A. M. Rostas, L. Ledernez, L. Dietel, L. Heidinger, M. Bergmann, M. Altenburger, R. Bruch, G. Urban, E. Schleicher and S. Weber, Phys. Chem. Chem. Phys., 2020, Advance Article , DOI: 10.1039/C9CP05799D

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