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Non-covalent Sulfoxide…(Nitrosyl Group) Interactions Involving Coordinated Nitrosyl in a Ru(II) Nitrosyl Complex with α-Diimine Ligand: Structural and Computational Studies

Abstract

Investigation of the X-ray structure of the newly prepared [Ru(NO)(2,6isopPh2Aceq)Cl3] (2,6isopPh2Aceq = bis(2,6-diisopropylphenylimino)acenaphthequinone) complex revealed for the first time the π-hole interaction involving the coordinated nitrosyl group with DMSO as solvent of crystallization in the crystal lattice. Processing of CSD data showed only one reported structure. The significant feature of the structure is the presence of n→π*, π→σ*, and n→σ* interactions due to the coordinated nitrosyl and chloro groups and DMSO.

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Supplementary files

Article information


Submitted
22 Jul 2020
Accepted
04 Oct 2020
First published
05 Oct 2020

CrystEngComm, 2020, Accepted Manuscript
Article type
Communication

Non-covalent Sulfoxide…(Nitrosyl Group) Interactions Involving Coordinated Nitrosyl in a Ru(II) Nitrosyl Complex with α-Diimine Ligand: Structural and Computational Studies

R. Kia, CrystEngComm, 2020, Accepted Manuscript , DOI: 10.1039/D0CE01063D

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