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Issue 40, 2020
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A highly stable octa-coordinated energetic complex

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Abstract

The quest for high-energy-density materials (HEDMs) based on transition metal complexes is focused on low-coordinate species. High-coordinate analogues are extremely rare. Here, the first example of a highly energetic complex (HEC) with the highest coordination number of eight in 3d metal coordination chemistry is reported. Its structure was confirmed by single crystal X-ray diffraction. Its remarkably high stability has also been investigated.

Graphical abstract: A highly stable octa-coordinated energetic complex

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Article information


Submitted
13 Jul 2020
Accepted
10 Sep 2020
First published
14 Sep 2020

CrystEngComm, 2020,22, 6591-6595
Article type
Communication

A highly stable octa-coordinated energetic complex

W. Tong, M. Bian, Y. Feng, T. Zhang, S. Hu and L. Yang, CrystEngComm, 2020, 22, 6591
DOI: 10.1039/D0CE01008A

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