Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.



Design, synthesis and investigations of a series of energetic salts through the variation of amines and concentration of picrate anions

Author affiliations

Abstract

Eight new energetic salts combining N-bases (amines) with picrate ions were synthesized in high yields and characterized by NMR (1H and 13C), IR spectroscopy, elemental analysis, and differential thermal analysis. Single-crystal structural studies were performed to confirm the structures, packing, and various interactions in the salts. Interestingly, salts 1 and 7 exist in different polymorphic forms and the effect of solvent on polymorphism was examined (i.e. solvatomorphism). Thermal stability and impact and friction sensitivities were also determined to understand the relationship between their structures and properties. Salt 3 with hydrazinium cations showed higher performance (d = 1.82 g cm−3; Td = 255.2 °C; D = 7.95 km s−1; P = 28.2 GPa; IS ≥ 30 J; FS ≥ 350 N) towards energetic applications. However, salts 4, 7, and 8 also exhibit good performance parameters, which are marginally better as compared to TNT. The tuning of the physiochemical properties and performances was carried out with the modification of the cationic-amine molecules and the molar ratio of the reactants.

Graphical abstract: Design, synthesis and investigations of a series of energetic salts through the variation of amines and concentration of picrate anions

Back to tab navigation

Supplementary files

Article information


Submitted
27 May 2020
Accepted
11 Jun 2020
First published
15 Jun 2020

CrystEngComm, 2020, Advance Article
Article type
Paper

Design, synthesis and investigations of a series of energetic salts through the variation of amines and concentration of picrate anions

R. S. Mathpati, S. Dharavath, N. Kumar, V. D. Ghule, A. K. Paul and R. K. Tittal, CrystEngComm, 2020, Advance Article , DOI: 10.1039/D0CE00772B

Social activity

Search articles by author

Spotlight

Advertisements