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2D-metal–organic coordination polymers of lanthanides (La(iii), Pr(iii) and Nd(iii)) with redox-active dioxolene bridging ligands

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Abstract

The synthesis, crystal structure, thermal stability, porosity and magnetic properties of three new layered coordination polymers [(M2(pQ)3)·4DMAA]n (M3+ = La3+ (1), Pr3+ (2), Nd3+ (3); pQ2− – the dianionic form of 2,5-dihydroxy-3,6-di-tert-butyl-para-quinone; DMAA = N,N′-dimethylacetamide) are reported. The coordination polymers obtained were investigated by solid-state electrochemistry which demonstrates multistep one-electron transformations caused by the presence of redox-active dioxolene ligands.

Graphical abstract: 2D-metal–organic coordination polymers of lanthanides (La(iii), Pr(iii) and Nd(iii)) with redox-active dioxolene bridging ligands

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Article information


Submitted
26 May 2020
Accepted
22 Jun 2020
First published
22 Jun 2020

CrystEngComm, 2020, Advance Article
Article type
Communication

2D-metal–organic coordination polymers of lanthanides (La(III), Pr(III) and Nd(III)) with redox-active dioxolene bridging ligands

A. D. Kharitonov, O. Y. Trofimova, I. N. Meshcheryakova, G. K. Fukin, M. N. Khrizanforov, Y. H. Budnikova, A. S. Bogomyakov, R. R. Aysin, K. A. Kovalenko and A. V. Piskunov, CrystEngComm, 2020, Advance Article , DOI: 10.1039/D0CE00767F

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