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Issue 26, 2020
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Carbon dioxide induced structural phase transition in metal–organic frameworks CPO-27

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Abstract

A phase transition occurs in metal–organic framework CPO-27-M (M = Co and Zn) below ∼110 K in CO2 atmosphere. The phase change involves the collective rearrangement of the inorganic chains and the organic ligands of the honeycomb framework. The new phase represents a superstructure of the original unit cell with doubled a and b axes, in which the cylindrical pore of the original phase transforms into two different pores.

Graphical abstract: Carbon dioxide induced structural phase transition in metal–organic frameworks CPO-27

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Article information


Submitted
27 Apr 2020
Accepted
10 Jun 2020
First published
10 Jun 2020

CrystEngComm, 2020,22, 4353-4358
Article type
Communication

Carbon dioxide induced structural phase transition in metal–organic frameworks CPO-27

B. Pato-Doldán, M. H. Rosnes, D. Chernyshov and P. D. C. Dietzel, CrystEngComm, 2020, 22, 4353
DOI: 10.1039/D0CE00632G

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