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Metal removal from the secondary building unit of bio-MOF-1 by adenine N6-alkylation while retaining the overall 3D porous topology

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Abstract

A novel approach to modify the SBU of the well-known bio-MOF-1 by reducing the nuclearity of the metal cluster while retaining the topology of the anionic 3D framework is reported. The resulting BioMOF is prone to accept H ions from the organic counterions providing a route to obtain neutral frameworks.

Graphical abstract: Metal removal from the secondary building unit of bio-MOF-1 by adenine N6-alkylation while retaining the overall 3D porous topology

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Article information


Submitted
27 Apr 2020
Accepted
11 May 2020
First published
11 May 2020

CrystEngComm, 2020, Advance Article
Article type
Communication

Metal removal from the secondary building unit of bio-MOF-1 by adenine N6-alkylation while retaining the overall 3D porous topology

A. García-Raso, A. Terrón, Y. Roselló, A. Frontera, O. Castillo, G. Beobide, S. Pérez-Yáñez, E. C. Escudero-Adán and J. J. Fiol, CrystEngComm, 2020, Advance Article , DOI: 10.1039/D0CE00631A

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