Issue 25, 2020
From the journal:

CrystEngComm

Metal removal from the secondary building unit of bio-MOF-1 by adenine N6-alkylation while retaining the overall 3D porous topology†

Angel García-Raso, ORCID logo a   Angel Terrón, ORCID logo a   Yannick Roselló, ORCID logo a   Antonio Frontera, ORCID logo a   Oscar Castillo, ORCID logo *bc   Garikoitz Beobide, ORCID logo bc   Sonia Pérez-Yáñez, ORCID logo bc   Eduardo C. Escudero-Adán ORCID logo d  and  Juan J. Fiol ORCID logo *a  

* Corresponding authors

a Departamento de Química, Universitat de les Illes Balears, Crta. de Valldemossa km 7.5, 07122 Palma, Baleares, Spain
E-mail: jfa950@uib.es

b Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, UPV/EHU, Apartado 644, 48080 Bilbao, Spain
E-mail: oscar.castillo@ehu.eus

c Basque Ctr Mat Applicat & Nanostruct, BCMat, UPV EHU Sci Pk, Leioa 48940, Spain

d Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST), Avinguda Països Catalans, 16, 43007 Tarragona, Spain

Abstract

A novel approach to modify the SBU of the well-known bio-MOF-1 by reducing the nuclearity of the metal cluster while retaining the topology of the anionic 3D framework is reported. The resulting BioMOF is prone to accept H ions from the organic counterions providing a route to obtain neutral frameworks.

Graphical abstract: Metal removal from the secondary building unit of bio-MOF-1 by adenine N6-alkylation while retaining the overall 3D porous topology

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Article information

DOI
https://doi.org/10.1039/D0CE00631A
Article type
Communication
Submitted
27 Apr 2020
Accepted
11 May 2020
First published
11 May 2020

CrystEngComm, 2020,22, 4201-4205

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Metal removal from the secondary building unit of bio-MOF-1 by adenine N6-alkylation while retaining the overall 3D porous topology

A. García-Raso, A. Terrón, Y. Roselló, A. Frontera, O. Castillo, G. Beobide, S. Pérez-Yáñez, E. C. Escudero-Adán and J. J. Fiol, CrystEngComm, 2020, 22, 4201 DOI: 10.1039/D0CE00631A

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