Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.



Conductive zigzag Pd(iii)–Br chain complex realized by a multiple-hydrogen-bond approach

Author affiliations

Abstract

Coexistence of zigzag structure and the uncommon Pd(III) oxidation state in quasi-1D halogen-bridged metal complexes was realized in a conductive Br-bridged Pd chain complex, [Pd(dabdOH)2Br]SO4·3H2O (2), for the first time. Intra- and interchain hydrogen-bond networks among the (2S,3S)-2,3-diaminobutane-1,4-diol (dabdOH) ligand and SO42− and H2O molecules support this unusual structure and electronic state. The electrical conductivity of 2 reached 0.05 S cm−1 at room temperature.

Graphical abstract: Conductive zigzag Pd(iii)–Br chain complex realized by a multiple-hydrogen-bond approach

Back to tab navigation

Supplementary files

Article information


Submitted
04 Mar 2020
Accepted
05 May 2020
First published
05 May 2020

CrystEngComm, 2020, Advance Article
Article type
Paper

Conductive zigzag Pd(III)–Br chain complex realized by a multiple-hydrogen-bond approach

M. R. Mian, U. Afrin, H. Iguchi, S. Takaishi, T. Yoshida, T. Miyamoto, H. Okamoto, H. Tanaka, S. Kuroda and M. Yamashita, CrystEngComm, 2020, Advance Article , DOI: 10.1039/D0CE00332H

Social activity

Search articles by author

Spotlight

Advertisements