Conductive zigzag Pd(iii)–Br chain complex realized by a multiple-hydrogen-bond approach

Abstract

Coexistence of zigzag structure and the uncommon Pd(III) oxidation state in quasi-1D halogen-bridged metal complexes was realized in a conductive Br-bridged Pd chain complex, [Pd(dabdOH)₂Br]SO₄·3H₂O (2), for the first time. Intra- and interchain hydrogen-bond networks among the (2S,3S)-2,3-diaminobutane-1,4-diol (dabdOH) ligand and SO₄²⁻ and H₂O molecules support this unusual structure and electronic state. The electrical conductivity of 2 reached 0.05 S cm⁻¹ at room temperature.