Issue 19, 2020

New pronounced progress in the synthesis of group 5 polyoxometalates

Abstract

The chemistry of polyoxomolybdates and polyoxotungstates has been systematically developed since their first discovery more than 100 years ago. In contrast, significant progress in the related chemistries of polyoxovanadates, polyoxoniobates and polyoxotantalates was mainly made during the last few years. This highlight summarizes new synthetic approaches for the generation of high-nuclearity group 5 polyoxometalates and discusses the synthetic conditions influencing product formation. The application of new precursors allows rational syntheses of group 5 polyoxometalates. The importance of the knowledge of the species in liquid media is also discussed and results of in situ investigations are presented.

Graphical abstract: New pronounced progress in the synthesis of group 5 polyoxometalates

Supplementary files

Article information

Article type
Highlight
Submitted
02 Mar 2020
Accepted
08 Apr 2020
First published
20 Apr 2020

CrystEngComm, 2020,22, 3254-3268

New pronounced progress in the synthesis of group 5 polyoxometalates

J. Dopta, L. K. Mahnke and W. Bensch, CrystEngComm, 2020, 22, 3254 DOI: 10.1039/D0CE00315H

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