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Issue 13, 2020
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A multiple hydrogen-bonded three-dimensional supramolecular architecture composed of a unique three-fold interlocked anionic Zn(ii)-coordination architecture

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Abstract

An unprecedented three-dimensional multiple hydrogen bonded supramolecular framework containing an interlocked three-fold self-knitting structural topology, which is based on a pseudo graphene-like unweaving monolayer of a Zn(II)-coordination complex, is obtained via a solvothermal synthesis method. Two different large cavities are generated in this supramolecular architecture. Furthermore, the investigation of the Hirshfeld surface analysis reproduces the results of an X-ray crystal structure analysis and expounds the intermolecular interactions experienced by complexes in a visual manner.

Graphical abstract: A multiple hydrogen-bonded three-dimensional supramolecular architecture composed of a unique three-fold interlocked anionic Zn(ii)-coordination architecture

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Supplementary files

Article information


Submitted
06 Feb 2020
Accepted
25 Feb 2020
First published
26 Feb 2020

CrystEngComm, 2020,22, 2283-2287
Article type
Communication

A multiple hydrogen-bonded three-dimensional supramolecular architecture composed of a unique three-fold interlocked anionic Zn(II)-coordination architecture

H. Ke, Q. Chen, J. Liao and C. Lu, CrystEngComm, 2020, 22, 2283
DOI: 10.1039/D0CE00177E

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