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Doping of metal-free molecular perovskite with hexamethylenetetramine to create non-centrosymmetric defects

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Abstract

The metal-free perovskite (dabcoH22+)(NH4)Br (d-Br) (dabco: 1,4-diazabicyclo[2.2.2]octane) was doped with non-centrosymmetric hexamethylenetetramine. The dopant was not structurally adapted to the original perovskite lattice, and thus caused structural fluctuations in the lattice and increased the thermal motion in the surrounding dabcoH22+.

Graphical abstract: Doping of metal-free molecular perovskite with hexamethylenetetramine to create non-centrosymmetric defects

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Article information


Submitted
05 Feb 2020
Accepted
26 Feb 2020
First published
27 Feb 2020

CrystEngComm, 2020, Advance Article
Article type
Communication

Doping of metal-free molecular perovskite with hexamethylenetetramine to create non-centrosymmetric defects

H. Morita, R. Tsunashima, S. Nishihara and T. Akutagawa, CrystEngComm, 2020, Advance Article , DOI: 10.1039/D0CE00173B

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