Jump to main content
Jump to site search


Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical Rh III4Zn II4 cluster with twelve carboxylate arms

Author affiliations

Abstract

Treatment of an octanuclear RhIII4ZnII4 cluster containing 12 free carboxylate groups, K6[Rh4Zn4O(L-cys)12] (K6[1], L-H2cys = L-cysteine), with inorganic acids (HX = HBr, H2SO4) produced ionic crystals of [H91]X3 composed of nona-protonated [H91]3+ cations and X anions. The H-bonded metallosupramolecular helices in [H91]X3, which showed proton conductivity and ammonia adsorption, were controlled by the employed inorganic anions.

Graphical abstract: Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

Back to tab navigation

Supplementary files

Article information


Submitted
29 Jan 2020
Accepted
17 Feb 2020
First published
19 Feb 2020

CrystEngComm, 2020, Advance Article
Article type
Communication

Hydrogen-bonded metallosupramolecular helices composed of a nona-protonated spherical RhIII4ZnII4 cluster with twelve carboxylate arms

U. Yamashita, N. Yoshinari, R. Sodkhomkhum, N. Meundaeng and T. Konno, CrystEngComm, 2020, Advance Article , DOI: 10.1039/D0CE00133C

Social activity

Search articles by author

Spotlight

Advertisements