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Core–shell metal–macrocycle framework (MMF): spatially selective dye inclusion through core-to-shell anisotropic transport along crystalline 1D-channels connected by epitaxial growth

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Abstract

Designing unique core–shell porous crystals is key to the development of anisotropically functionalised materials. Herein we report the facile preparation of a core–shell metal–macrocycle framework (MMF) containing continuous 1D-channels via an epitaxial growth procedure. Methyl orange loaded in the core was found to be anisotropically transported to the shell along the heterogeneously hybridised 1D-channels.

Graphical abstract: Core–shell metal–macrocycle framework (MMF): spatially selective dye inclusion through core-to-shell anisotropic transport along crystalline 1D-channels connected by epitaxial growth

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Article information


Submitted
25 Jan 2020
Accepted
04 Feb 2020
First published
07 Feb 2020

CrystEngComm, 2020, Advance Article
Article type
Communication

Core–shell metal–macrocycle framework (MMF): spatially selective dye inclusion through core-to-shell anisotropic transport along crystalline 1D-channels connected by epitaxial growth

S. Tashiro, S. Mitsui, D. W. Burke, R. Kubota, N. Matsushita and M. Shionoya, CrystEngComm, 2020, Advance Article , DOI: 10.1039/D0CE00120A

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