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Synthesis, structure, magnetic and luminescent properties of two dysprosium Single-Molecule Magnets based on phenoxide dye ligands.

Abstract

We report here two dysprosium complexes based on phenoxide-based emissive ligands 1-(2,4-dimetylphenylazo)-2-naphtholate (L1) and anthracenolate (L2). While 1 is a dinuclear homoleptic complex [Dy2(L1)6]•2C7H8 exhibiting a zero-field slow relaxation of the magnetization, 2 is a mononuclear complex [Dy(L2)3(py)3] (py = pyridine) showing a field-induced relaxation.

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Article information


Submitted
15 Jan 2020
Accepted
05 Feb 2020
First published
06 Feb 2020

CrystEngComm, 2020, Accepted Manuscript
Article type
Communication

Synthesis, structure, magnetic and luminescent properties of two dysprosium Single-Molecule Magnets based on phenoxide dye ligands.

J. Long, A. N. Selikhov, E. Mamontova, K. A. Lyssenko, Y. Guari, J. Larionova and A. Trifonov, CrystEngComm, 2020, Accepted Manuscript , DOI: 10.1039/D0CE00055H

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