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Lilac flower-shaped ZnCo₂O₄ electrocatalyst for efficient methanol oxidation and oxygen reduction reactions in alkaline medium

Abstract

The oxygen reduction reaction (ORR) plays a vital role in electrochemical energy conversion and energy storage devices such as metal-air batteries and alkaline fuel cells. The development of a proficient, noble metal-free catalyst for electrocatalytic ORRs is one of the main challenges impeding fuel cell research. ZnCo₂O₄ lilac flowers (LFs) were synthesized using a rapid microwave irradiation method, at 160 °C for 15 min, followed by annealing, at 400 °C for 4 hrs.XRD confirms the high crystallinity and phase purity. HR-TEM images show several smaller, primary nanoparticle building blocks, which combine to form lilac flower-like structures, through a self-assembly process. The methanol oxidation reaction (MOR) and ORR were evaluated using ZnCo₂O₄ LFs as the catalyst. The stability and durability of the ZnCo₂O₄ LFs catalyst were analyzed by chronoamperometry (CA) measurements and CA responses for ORR on ZnCo₂O₄ LFs at -0.5 V vs. RHE, in O₂- saturated 0.1 M KOH electrolyte. These tests showed that the catalyst exhibited remarkable MOR and ORR activity in alkaline media.

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Supplementary files

Article information


Submitted
07 Jan 2020
Accepted
29 Feb 2020
First published
03 Mar 2020

CrystEngComm, 2020, Accepted Manuscript
Article type
Paper

Lilac flower-shaped ZnCo₂O₄ electrocatalyst for efficient methanol oxidation and oxygen reduction reactions in alkaline medium

T. V. M. Sreekanth, N. pc, K.C. Devarayapalli, J. Shim and Y. K, CrystEngComm, 2020, Accepted Manuscript , DOI: 10.1039/D0CE00024H

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