Issue 10, 2020
From the journal:

CrystEngComm

Hydrazone–aromatic interaction: the vital role in molecular self-assembly of benzaldehyde hydrazones†

Zhenfeng Zhang ORCID logo *a  and  Dejun Chena  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Henan Key Laboratory of Organic Functional Molecule and Drug Innovation, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan 453007, China
E-mail: zzf@htu.cn
Fax: +86 373 3326336
Tel: +86 373 3326335

Abstract

A scarce NN[double bond, length as m-dash]C⋯π interaction, which plays an essential role in defining the crystal packing patterns, has been found widespread in benzaldehyde (cyanoacetyl)hydrazones, and is rationalized by density functional theory calculations. Molecular electrostatic potential analyses offer effective further support for the interaction.

Graphical abstract: Hydrazone–aromatic interaction: the vital role in molecular self-assembly of benzaldehyde hydrazones

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Article information

DOI
https://doi.org/10.1039/C9CE01978B
Article type
Communication
Submitted
15 Dec 2019
Accepted
06 Feb 2020
First published
07 Feb 2020

CrystEngComm, 2020,22, 1691-1694

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Hydrazone–aromatic interaction: the vital role in molecular self-assembly of benzaldehyde hydrazones

Z. Zhang and D. Chen, CrystEngComm, 2020, 22, 1691 DOI: 10.1039/C9CE01978B

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