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Hydrazone-aromatic interaction: the vital role in molecular self-assembly of benzaldehyde hydrazones

Abstract

A scarce NN=C…π interaction, which plays an essential role in defining the crystal packing patterns, has been found widespread in benzaldehyde (cyanoacetyl)hydrazones, and is rationalized by density functional theory calculations. Molecular electrostatic potential analyses offer an effective further support for the interaction.

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Article information


Submitted
15 Dec 2019
Accepted
06 Feb 2020
First published
07 Feb 2020

CrystEngComm, 2020, Accepted Manuscript
Article type
Communication

Hydrazone-aromatic interaction: the vital role in molecular self-assembly of benzaldehyde hydrazones

Z. Zhang and D. Chen, CrystEngComm, 2020, Accepted Manuscript , DOI: 10.1039/C9CE01978B

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