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Role of the B′-site metal ion in the framework structures and dielectric transitions in host–guest type cyanometalates (HIm)2[B′Co(CN)6] (HIm = imidazolium cation)

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Abstract

The B′-site alkali metal ion (B′ = Li, Na, K, and Rb) in a series of hexacyanocobaltate-based organic–inorganic hybrid compounds (HIm)2[B′Co(CN)6] (HIm = imidazolium cation) plays a key role in the change of the framework structures and the dynamic behaviours of the guest. As a result, the associated bulk dielectric properties are also changed.

Graphical abstract: Role of the B′-site metal ion in the framework structures and dielectric transitions in host–guest type cyanometalates (HIm)2[B′Co(CN)6] (HIm = imidazolium cation)

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Article information


Submitted
04 Nov 2019
Accepted
30 Jan 2020
First published
31 Jan 2020

CrystEngComm, 2020, Advance Article
Article type
Paper

Role of the B′-site metal ion in the framework structures and dielectric transitions in host–guest type cyanometalates (HIm)2[B′Co(CN)6] (HIm = imidazolium cation)

C. Shi, Z. Gong, Q. Wang, X. Han and W. Zhang, CrystEngComm, 2020, Advance Article , DOI: 10.1039/C9CE01739A

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