Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

Ryuta Ishikawa; Shunya Ueno; Hiroaki Iguchi; Brian K. Breedlove; Masahiro Yamashita; Satoshi Kawata

doi:10.1039/C9CE01580A

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Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear Cu^II complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals†

Ryuta Ishikawa,

*^a Shunya Ueno,^a Hiroaki Iguchi,

^b Brian K. Breedlove,

^b Masahiro Yamashita^bcd and Satoshi Kawata

Author affiliations

* Corresponding authors

^a Department of Chemistry, Faculty of Science, Fukuoka University, 8-19-1 Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan
E-mail: ryutaishikawa@fukuoka-u.ac.jp

^b Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai, Miyagi 980-8578, Japan

^c Advanced Institute for Materials Research (AIMR), Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai, Miyagi 980-8577, Japan

^d School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

Abstract

The reaction of a doubly bis(2-pyridyl)pyrazolate (bpypz⁻) bridged dinuclear cationic copper(II) complex with 7,7′,8,8′-tetracyano-p-quinodimethanido radicals (TCNQ˙⁻) afforded a tetranuclear complex, [Cu₄(μ-bpypz)₄(μ-TCNQ)₂](TCNQ)₂ (1), which self-assembles into a three-dimensional supramolecular coordination architecture via complementary weak coordination bonding and π–π stacking interactions.

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Article information

DOI: https://doi.org/10.1039/C9CE01580A
Article type: Communication
Submitted: 07 Oct 2019
Accepted: 30 Oct 2019
First published: 31 Oct 2019

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CrystEngComm, 2020,22, 159-163

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Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear Cu^II complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

R. Ishikawa, S. Ueno, H. Iguchi, B. K. Breedlove, M. Yamashita and S. Kawata, CrystEngComm, 2020, 22, 159 DOI: 10.1039/C9CE01580A

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