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Issue 98, 2020
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A transient lanthanum phosphinidene complex

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Abstract

Deprotonation of the terminal phosphido complex (PN)2La(PHMes) (1) results in the C–H-activation of one of the PN ligands, formally retaining the PHMes group. The reaction mechanism and the possible involvement of the transient phosphinidene complex 2 are investigated by theoretical and chemical means including a deuteration experiment employing (PN)2La(PDMes) (1-d). Furthermore, the thermal stability of product [K(2.2.2-cryptand)][(PN)(PNcyclo)La(PHMes)] (3b) is examined, giving the diphosphido complex [K(2.2.2-cryptand)][(PN)2La(P2Mes2)] (6).

Graphical abstract: A transient lanthanum phosphinidene complex

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Supplementary files

Article information


Submitted
06 Oct 2020
Accepted
06 Nov 2020
First published
06 Nov 2020

Chem. Commun., 2020,56, 15410-15413
Article type
Communication

A transient lanthanum phosphinidene complex

F. A. Watt, K. N. McCabe, R. Schoch, L. Maron and S. Hohloch, Chem. Commun., 2020, 56, 15410
DOI: 10.1039/D0CC06670B

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