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Issue 95, 2020
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Chemiluminescent read-out of para-fluoro-thiol reaction events

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Abstract

We exploit the fluoride that is released via the para-fluoro-thiol reaction (PFTR) to cleave silyl ethers, turning the PFTR into an effective self-reporting chemiluminescence (CL) probe. The cleavage induces chemiluminescence and hence provides an optical read-out for the conversion of the PFTR. The PFTR chemiluminescence read-out is established on small molecule thiols, and subsequently expanded to polymers and networks.

Graphical abstract: Chemiluminescent read-out of para-fluoro-thiol reaction events

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Article information


Submitted
21 Sep 2020
Accepted
05 Nov 2020
First published
05 Nov 2020

Chem. Commun., 2020,56, 14996-14999
Article type
Communication

Chemiluminescent read-out of para-fluoro-thiol reaction events

F. R. Bloesser, F. Cavalli, S. L. Walden, L. Barner and C. Barner-Kowollik, Chem. Commun., 2020, 56, 14996
DOI: 10.1039/D0CC06356H

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